This problem was asked in JEE 2015. It states:

If the degeneracy of hydrogen atom in second excited state (\(n=3\)) is 9 then find the degeneracy of hydride anion i.e. \(\ce{H^-}\) ion in second excited state.

**Note**: electronic spin is not to be considered here.

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TopNewestBefore I answer this, let me ask you a question that will be key to understanding what's happening here:

Why is the degeneracy of hydrogen atom 9 when n = 3? – Ameya Daigavane · 8 months, 2 weeks ago

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– Dipanjan Chowdhury · 8 months, 2 weeks ago

I think because of the one 3s three 3p and five 3d orbitals which are not excited as have no electron and as a whole exhibit degeneracyLog in to reply

But for H-, there are two electrons. The orbitals' energies now depend on l (the azimuthal quantum number that differentiates between s,p, d, f and so on.) like, \( 1s < 2s < 2p < 3s < 3p ...\)

Now the ground state of H- is \(1s^2 \).

The 1st excited state is \( 1s^1 2s^1 \).

The second excited state is \( 1s^1 2s^0 2p^1 \) (Compare with H atom for which the 2nd excited state is \( 3s^1 \).)

But there are 3 p orbitals for the electron to 'choose' between when making the transition from first excited state to second excited state.

So the degeneracy is 3. Hope this helps. – Ameya Daigavane · 8 months, 2 weeks ago

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– Dipanjan Chowdhury · 8 months, 2 weeks ago

Absolutely clear, Sir. Thank You . :D I was unaware of this sort of splitting.Log in to reply