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Chemistry - Partition Law

Problem Set


What will the scientists do if they want to extract and help purify a desired product from a reaction mixture? This is when the Partition Law(or Distribution Law) saves the day!

First, we set some variables:

Let \(A\) and \(B\) be two immiscible liquids(cannot dissolve or react with each other), such as water and oil.

Let the solubility of \(X\) in liquid \(A\) be \(s_A\).

Let the solubility of \(X\) in liquid \(B\) be \(s_B\).

Now, we do the following steps:

1) Mix solute \(X\) into the mixture of liquid \(A\) and \(B\).

2) Stir them constantly and wait till liquid \(A\) and liquid \(B\) are divided into two layers(they will as they cannot dissolve each other).

3) Now, solute \(X\) is dissolved in both solvent \(A\) and solvent \(B\) but the concentration is different.

This is what Partition Law wants to deliver to us.

Definition: At a fixed temperature, when a solute is added to a system consisting of two solvent, it will distribute itself between the two solvent in proportion to its solubility in each of the two solvent separately.

If we express the definition in formula, it will be

\(K=\frac{s_A}{s_B}\)

where \(K\) is the partition coefficient.

If at \(40^\circ C\), the solubility of \(X\) is \(50g/100g\) water and \(100g/100g\) ether, then the partition coefficient

\(K=\frac{s_{water}}{s_{ether}}=\frac{50g/100g}{100g/100g}=\frac{1}{2}\).

Now there is an example:

If \(1L\) water can dissolve \(100g\) organic compound \(X\) and I use \(1L\) ether to extract it, what is the mass in grams of \(X\) are left in the ether layer?

Details:

\(K=\frac{s_{H_2O}}{s_{ether}}=\frac{1}{2}\)

Solution:

Let the amount extracted be \(x\) \(g\).

The solubility of \(X\) in water is \(s_{H_2O}=\frac{(100-x)g}{1L}\)

The solubility of \(X\) in ether is \(s_{ether}=\frac{xg}{1L}\)

Then,

\(K=\frac{s_{H_2O}}{s_{ether}}\)

\(\frac{1}{2}=\frac{\frac{(100-x)g}{1L}}{\frac{(x)g}{1L}}\)

\(x=66.7\) \(g\)

So, the mass of \(X\) that left in the ether layer is \(66.7\) \(g\).

**Note that I use \(g/L\) as the unit of solubility instead of \(g/g\) in my note before.

Solubility of \(5g/1L\) water means \(1L\) water can dissolve a maximum of \(5g\) of that solute.

Solubility of \(5g/100g\) water means \(100g\) water can dissolve a maximum of \(5g\) of that solute.

So, the unit does not make any changes to the answer as long as we use the same unit. As the example above, we cannot use a unit of solubility written as \(g/L\) while the other written as \(g/g\).

Note by Christopher Boo
3 years, 2 months ago

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Why is \(x = 66.7g\)? Daniel Lim · 3 years, 1 month ago

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@Daniel Lim \(\frac{1}{2}=\frac{100-x}{x}\)

\(x=200-2x\)

\(3x=200\)

\(x=66.7\) Christopher Boo · 3 years, 1 month ago

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@Christopher Boo Oh... Thanks Daniel Lim · 3 years, 1 month ago

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Thx for the information Benjamin Setiawan · 11 months, 2 weeks ago

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What does "extract" mean? Daniel Lim · 3 years, 1 month ago

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@Daniel Lim Thanks Daniel Lim · 3 years, 1 month ago

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@Daniel Lim To obtain a substance by chemical or mechanical action, as by pressure, distillation, or evaporation. (Google) Christopher Boo · 3 years, 1 month ago

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@Daniel Lim Literal Definition: to remove/separate a certain substance(useful) from another substance through various Physical and Chemical methods. Anish Puthuraya · 3 years, 1 month ago

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Thanks for the post! Never learned this back in secondary school. Marissa Chong · 3 years, 1 month ago

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Thanks Christopher for this post which is completely new to me. Soham Dibyachintan · 3 years, 2 months ago

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Peter Taylor-

I like the way you added the problems into the notes. However, I don't know how to add a line between the problem and the note. Can you teach me, please? Christopher Boo · 3 years, 2 months ago

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@Christopher Boo To make a line between things use 3 dashes in a row at the beginning of the line. For instance, this is a picture of the markdown on your problem set in the first note.

Imgur

Imgur

Peter Taylor Staff · 3 years, 2 months ago

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@Peter Taylor Thanks! Christopher Boo · 3 years, 2 months ago

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@Christopher Boo I also took the liberty of making you a picture. It's not the best, and it is a little bit of stretch, seeing as the post is mostly about partitioning and not about miscibility. If you don't like it, I can take the picture away. Peter Taylor Staff · 3 years, 2 months ago

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@Peter Taylor The picture is very nice, thanks! Christopher Boo · 3 years, 2 months ago

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nice.. :) Joyan Florenz Delos Verges · 3 years, 2 months ago

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good post Fauline St · 3 years, 2 months ago

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Good Post... Anish Puthuraya · 3 years, 2 months ago

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