**Problem Set**

What will the scientists do if they want to extract and help purify a desired product from a reaction mixture? This is when the **Partition Law**(or **Distribution Law**) saves the day!

First, we set some variables:

Let \(A\) and \(B\) be two **immiscible liquids**(cannot dissolve or react with each other), such as water and oil.

Let the solubility of \(X\) in liquid \(A\) be \(s_A\).

Let the solubility of \(X\) in liquid \(B\) be \(s_B\).

Now, we do the following steps:

1) Mix solute \(X\) into the mixture of liquid \(A\) and \(B\).

2) Stir them constantly and wait till liquid \(A\) and liquid \(B\) are divided into two layers(they will as they cannot dissolve each other).

3) Now, solute \(X\) is dissolved in both solvent \(A\) and solvent \(B\) but the **concentration** is different.

This is what **Partition Law** wants to deliver to us.

Definition: At a **fixed temperature**, when a solute is added to a system consisting of two solvent, it will distribute itself between the two solvent in proportion to its solubility in each of the two solvent separately.

If we express the definition in formula, it will be

\(K=\frac{s_A}{s_B}\)

where \(K\) is the **partition coefficient**.

If at \(40^\circ C\), the solubility of \(X\) is \(50g/100g\) water and \(100g/100g\) ether, then the partition coefficient

\(K=\frac{s_{water}}{s_{ether}}=\frac{50g/100g}{100g/100g}=\frac{1}{2}\).

Now there is an example:

If \(1L\) water can dissolve \(100g\) organic compound \(X\) and I use \(1L\) ether to extract it, what is the mass in **grams** of \(X\) are left in the ether layer?

Details:

\(K=\frac{s_{H_2O}}{s_{ether}}=\frac{1}{2}\)

Solution:

Let the amount extracted be \(x\) \(g\).

The solubility of \(X\) in water is \(s_{H_2O}=\frac{(100-x)g}{1L}\)

The solubility of \(X\) in ether is \(s_{ether}=\frac{xg}{1L}\)

Then,

\(K=\frac{s_{H_2O}}{s_{ether}}\)

\(\frac{1}{2}=\frac{\frac{(100-x)g}{1L}}{\frac{(x)g}{1L}}\)

\(x=66.7\) \(g\)

So, the mass of \(X\) that left in the ether layer is \(66.7\) \(g\).

**Note that I use \(g/L\) as the unit of solubility instead of \(g/g\) in my note before.

Solubility of \(5g/1L\) water means \(1L\) water can dissolve a maximum of \(5g\) of that solute.

Solubility of \(5g/100g\) water means \(100g\) water can dissolve a maximum of \(5g\) of that solute.

So, the unit does not make any changes to the answer as long as we use the same unit. As the example above, we cannot use a unit of solubility written as \(g/L\) while the other written as \(g/g\).

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## Comments

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TopNewestWhy is \(x = 66.7g\)?

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\(\frac{1}{2}=\frac{100-x}{x}\)

\(x=200-2x\)

\(3x=200\)

\(x=66.7\)

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Oh... Thanks

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Thx for the information

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What does "extract" mean?

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Thanks

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To obtain a substance by chemical or mechanical action, as by pressure, distillation, or evaporation. (Google)

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Literal Definition: to remove/separate a certain substance(useful) from another substance through various Physical and Chemical methods.Log in to reply

Thanks for the post! Never learned this back in secondary school.

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Thanks Christopher for this post which is completely new to me.

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Peter Taylor-

I like the way you added the problems into the notes. However, I don't know how to add a line between the problem and the note. Can you teach me, please?

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To make a line between things use 3 dashes in a row at the beginning of the line. For instance, this is a picture of the markdown on your problem set in the first note.

Imgur

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Thanks!

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I also took the liberty of making you a picture. It's not the best, and it is a little bit of stretch, seeing as the post is mostly about partitioning and not about miscibility. If you don't like it, I can take the picture away.

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The picture is very nice, thanks!

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nice.. :)

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good post

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Good Post...

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